Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN 3]nickel(II) nitrate
نویسندگان
چکیده
In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-H⋯O, N-H⋯O and N-H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π-π inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [centroid-centroid distances = 3.592 (3) and 3.735 (3) Å].
منابع مشابه
Aqua(sulfato-κO)bis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN 3]iron(II)
In the title compound, [Fe(SO(4))(C(10)H(7)N(3)S)(2)(H(2)O)], the Fe(II) cation is sixfold coordinated by four N atoms from two 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one water O atom and one O atom of the sulfate dianion within a slightly distorted octa-hedral geometry. The cations and anions are connected by N-H⋯O and O-H⋯O hydrogen bonds into layers in the ab plane.
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